Article · Wikipedia archive · Last revised Jul 12, 2026

Ferroxyl indicator solution

Ferroxyl indicator, or rust indicator, is a solution containing potassium hexacyanoferrate(III) and phenolphthalein. It turns blue in the presence of Fe2+ ions, and pink in the presence of hydroxide (OH−) ions. It can be used to detect metal oxidation, and is often used to detect rusting in various situations. Sodium chloride may also be included in the solution for higher rate of corrosion.

Last revised
Jul 12, 2026
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Corrosion of iron nail with coiled copper in medium with ferroxyl indicator source ↗

Ferroxyl indicator, or rust indicator, is a solution containing potassium hexacyanoferrate(III) and phenolphthalein. It turns blue in the presence of Fe2+ ions, and pink in the presence of hydroxide (OH) ions. It can be used to detect metal oxidation, and is often used to detect rusting in various situations. Sodium chloride may also be included in the solution for higher rate of corrosion.

Formula

It can be prepared by dissolving 10g sodium chloride and 1g potassium hexacyanoferrate(III) in distilled water, adding 10 cm3 phenolphthalein indicator, then making up to 500 cm3 with distilled water.1

References

References

  1. "SALTERS ADVANCED CHEMISTRY A2 TECHNICIANS MANUAL" (PDF). benjamin-mills.com. p. 52.